新型手性钙钛矿材料的合成及其应用研究，钙钛矿手性超结构，高性能有机太阳能电池

龙官奎研究员，博士生导师，国家级青年人才项目入选者。2009年本科毕业于兰州大学化学化工学院，保送至南开大学化学学院攻读博士学位（师从陈永胜教授）。随后在天津化学化工协同创新中心、多伦多大学和南洋理工大学从事博士后工作，2020年9月加入南开大学独立开展科研工作。近年来发表论文120余篇，其中以第一作者及通讯作者身份发表论文30余篇，包括Nat. Photon., Nat. Rev. Mater., Nat. Commun., Angew. Chem. Int. Ed., Adv. Mater., Adv. Funct. Mater.和Adv. Energy Mater.等国际知名期刊。为国内外多个课题组提供了理论计算和机理研究方面的支撑，担任《Nano-Micro Letters》编辑部的Assistant Editor。

奖励荣誉：

国家青年人才项目

天津市青年人才项目

Solar RRL Online Symposium on Perovskite, WILEY, 2020 (最佳墙报奖)

博士生国家奖学金

兰州大学优秀本科毕业生

䇹政学者（2008年赴新竹清华大学交流，指导老师：张浩力/季昀教授）

本课题组诚聘助理研究员和师资博士后，欢迎成绩优异的2024级推免生和考研生联系！同时欢迎本科生提前进实验室和开展毕业设计！

1. Song, T.;† Wang, C.-Q.;† Lu, H.; Mu, X.-J.; Wang, B.-L.; Liu, J.-Z.; Ma, B.; Cao, J.; Sheng, C.-X.; Long, G.;* Wang, Q.;* Zhang, H.-L.;* Angew. Chem. Int. Ed. 2024, 63, e202400769

2. Niu, X.;† Zeng, Z.;† Wang, Z.; Lu, H.; Sun, B.; Zhang, H.-L.; Chen, Y.; Du, Y.;* Long, G.;* The First Chiral Cerium Halide towards Circularly-polarized Luminescence in the UV Region. Sci. China. Chem., 2024, DOI: 10.1007/s11426-024-1946-7

3. He, T.;† Lin, M.;† Wang, H.; Zhang, Y.; Chen, H.; Sun, C.-L.; Sun, Z.; Wang, X.-Y.; Zhang, H.-L.; Chen, Y.;* Long, G.;* Chiral cylindrical molecule with absorption dissymmetry factor towards theoretical limit of 2. Adv. Theory Simul., 2024, 7, 2300573

4. Lu, H.; He, T.; Wu, H.; Qi, F.; Wang, H.; Sun, B.; Shao, T.; Qiao, T.; Zhang, H.-L.; Sun, D.; Chen, Y.; Tang, Z.; Long, G.;* Chiral Magnetic Ruthenium Halide with Strong Antiferromagnetic Coupling. Adv. Funct. Mater. 2024, 34, 2308862

5. Wang, H.;† Yu, Y.;† Lu, H.; Wang, T.; Haruta, Y.; Wei, X.; Xing, G.; Saidaminov, M. I.; Zhou, Y.;* Long, G.;* Three-dimensional lead iodide perovskites based on complex ions. Mater. Adv. 2024, 5, 123

6. Luo, Z.; Wu, C.; Yan, M.; Yu, X.;* Yu, X.-M.;* Qian, Q.; Zhou, Y.; Zhang, H.; Li, Z.; Long, G.;* Enhancing detectivity of organic photodetectors through the biomass carbon quantum dots from sugarcane bagasse, Mater. Chem. Phys. 2024, 316, 129056

7. Gu X.;† Zeng, R.;† He, T.; Zhou, G.; Li, C.; Yu, N.; Han, F.; Hou, Y.; Lv, J.; Zhang, M.; Zhang, J.; Wei, Z.; Tang, Z.; Zhu, H.; Cai, Y.; Long, G.; Liu, F.;* Zhang, X.;* Huang, H.;* Simple-Structured Acceptor with Highly Interconnected Electron-Transport Pathway Enables High-Efficiency Organic Solar Cells. Adv. Mater. 2024, 36, 2401370

8. Han, Z.;† Zhang, C.;† He, T.;† Gao, J.; Hou, Y.; Gu, X.; Lv, J.; Yu, N.; Qiao, J.; Wang, S.; Li, C.; Zhang, J.; Wei, Z.; Peng, Q.; Tang, Z.; Hao, X.; Long, G.; Cai, Y.; Zhang, X.; Huang, H.; Precisely Manipulating Molecular Packing via Tuning Alkyl Side-Chain Topology Enabling High-Performance Nonfused-Ring Electron Acceptors. Angew. Chem. Int. Ed. 2024, 63, e202318143

9. Liu, J.; He, T.; Gong, Z.; Liang, N.; Feng, Y.;* Long, G.; Zhong, Y.; Yao, C.;* Rational Design of Circularly Polarized Luminescent Molecular Structures Toward NIR and Single Molecule White Light Emission. Adv. Optical Mater. 2024, 12, 2302486

10. Chang, C.; Lu, H.; Liu, Y.; Long, G.; Guo, X.;* Ji, X.;* Jin, Z.;* Novel CoV-LDH/GDY/CuI tandem double S-scheme heterojunction based on graphdiyne (g-C_nH_2n−2) toward photocatalytic hydrogen evolution. J. Mater. Chem. A 2024, 12, 4204

11. Wang, H.;† Li, J.;† Lu, H.; Gull, S.; Shao, T.; Zhang, Y.; He, T.-F.; Chen, Y.; He, T ;* Long, G.;* Chiral Hybrid Germanium(II) Halide with Strong Nonlinear Chiroptical Properties. Angew. Chem. Int. Ed. 2023, 62, e202309600

12. Zhang, Y.;† Chen, M.;† He, T.; Chen, H.; Zhang, Z.; Wang, H.; Lu, H.; Ling, Q.; Hu, Z.; Liu, Y.;* Chen, Y.;* Long, G.;* Highly Efficient and Stable FA-Based Quasi-2D Ruddlesden-Popper Perovskite Solar Cells by the Incorporation of β-Fluorophenylethanamine Cations. Adv. Mater. 2023, 35, 2210836

13. Liu, X.; Lu, H.; Zhu, S.; Cui, Z.; Li, Z.; Wu, S.; Xu, W.; Liang, Y.;* Long, G.;* Jiang H.;* Alloying-Triggered Phase Engineering of NiFe System via Laser-Assisted Al Incorporation for Full Water Splitting. Angew. Chem. Int. Ed. 2023, 62, e202300800

14. Fan, Z.;† Lu, H.;† Liu, Y.; Chang, C.; Guo, X.;* Long, G.;* Jin, Z.;* Distinctive graphdiyne coupled with phosphorylation NiFe-LDH S-scheme heterojunction for photocatalytic overall water splitting. Chem. Eng. J., 2023, 477, 147008

15. Ma, S.;† Sun, H.;† Chen, J.; Yu, Y.; Lu, H.; Wang, S.; Zhang, J.;* Zhao, J.;* Long, G.;* Wang, X.;* Stoichiometric and Chiral Stacking Tailoring of Dibenzocarbazole Analog-TCNB Charge-Transfer Cocrystals via Supramolecular Assembly for Variable Optical Behaviors. Adv. Opt. Mater. 2023, 11, 2203087

16. Chen, X.-H.; Lu, H., Wu, Z.; Wang, H.; Zhang, S.; Mei, S.;* Long, G.;* Zhang, Q.;* Yao C.* Structure regulation induced high capacity and ultra-stable cycling of conjugated organic cathodes for Li-ion batteries. J. Mater. Chem. A 2023, 11, 77-83

17. Chen, G., Li, Z., Huang, Z., Lu, H., Long, G., Pacheco, J. S. L. S., Tok, J. B. H., Gao, T. Z., Lei, Y., Zhou, J., Bao, Z., Effects of Transition Metals on Metal-Octaaminophthalocyanine-Based 2D Metal-Organic Frameworks. ACS Nano 2023, 17, 9611-9621

18. Li, J.*, Guo, Z., Li, P., Liu, J., Zhai, X., Chang, Z., Chang, W., Long, G., Niu, B.*, Guo, Y.*, Magnetic Fano resonance enhanced second-harmonic generation in chiral hybrid bismuth halides. Appl. Phys. Lett. 2023, 122, 091701

19. Yang, H.; Chen, X.; Chu, Y.; Sun, C.; Lu, H.; Yuan, M.; Zhang, Y.; Long, G.; Zhang, L.; Li, X.* A universal hydrochloric acid-assistant powder-to-powder strategy for quick and mass preparation of lead-free perovskite microcrystals. Light Sci. Appl. 2023, 12, 75

20. Yang, H.; Chen, X.; Lu, H.; Li, Y.; Sun, W.; Zhang, Y.;* Liu, X.; Long, G.; Zhang, L.;* Li, X.;* Self-Trapped Excitons-Based Warm-White Afterglow by Room-Temperature Engineering toward Intelligent Multi-Channel Information System. Adv. Funct. Mater. 2023, 33, 2311437

21. Liang, H., Bi, X., Chen, H., He, T., Lin, Y., Zhang, Y., Ma, K., Feng, W., Ma, Z., Long, G., Li, C., Kan, B., Zhang, H., Rakitin, O., Wan, X., Yao, Z.*, Chen, Y. *, A rare case of brominated small molecule acceptors for high-efficiency organic solar cells. Nat. Commun. 2023, 14, 4707

22. Chen, H., Zhang, Z., Wang, P., Zhang, Y., Ma, K., Lin, Y., Duan, T., He, T., Ma, Z., Long, G., Li, C., Kan, B.*, Yao, Z.*, Wan, X., Chen, Y.*, 3D acceptors with multiple A-D-A architectures for highly efficient organic solar cells. Energy Environ. Sci. 2023, 16, 1773-1782

23. Xu, Z.; Li, S.; Huang, F.; He, T.; Jia, X.; Liang, H.; Guo, Y.; Long, G.; Kan, B.; Yao, Z.;* Li, C.; Wan, X.; Chen, Y.;* Propeller vs Quasi-Planar 6-Cantilever Small Molecular Platforms with Extremely Two-Dimensional Conjugated Extension.Angew. Chem. Int. Ed. 2023, 62, e202311686

24. Yao, Z.;* Cao, X.; Bi, X.; He, T.; Li, Y.; Jia, X.; Liang, H.; Guo, Y.; Long, G.; Kan, B.; Li, C.; Wan, X.; Chen, Y.;* Complete Peripheral Fluorination of the Small-Molecule Acceptor in Organic Solar Cells Yields Efficiency over 19%. Angew. Chem. Int. Ed. 2023, 62, e202312630

25. Liang, H., Chen, H., Wang, P., Zhu, Y., Zhang, Y., Feng, W., Ma, K., Lin, Y., Ma, Z., Long, G., Li, C., Kan, B., Yao, Z.*, Zhang, H., Wan, X., Chen, Y.*, Molecular Packing and Dielectric Property Optimization through Peripheral Halogen Swapping Enables Binary Organic Solar Cells with an Efficiency of 18.77%. Adv. Funct. Mater. 2023, 33, 2301573

26. Feng, W., Ma, K., Song, G., Shao, T., Liang, H., Lu, S., Chen, Y., Long, G., Li, C., Wan, X., Yao, Z., Kan, B.*, Chen, Y.*, P-doped all-small-molecule organic solar cells with power conversion efficiency of 17.73%. Sci. China Chem. 2023, 66, 2371-2379

27. Chen, H.;†Cao, X.;†Wang, P.; Huang, F.; Zhang, Y.; Liang, H.; Bi, X.; He, T.; Feng, W.; Guo, Y.; Ma, Z.; Long, G.; Yao, Z.;* Kan, B.; Li, C.; Wan, X.; Chen, Y.;* A rare case of iodinated non-fullerene acceptors for high-performance organic solar cells without post-treatments. J. Mater. Chem. A, 2023, 11, 25368-25376

28. Guo, J.;†Ji, X.;†Cao, X.; He, T.; Liang, H.; Shi, W.; Xu, Z.; Wang, R.; Guo, Y.;* Yao, Z.;* Wan, X.; Long, G.; Li, C.; Chen, Y.;* A narrow-bandgap non-fullerene acceptor constructed with an S,N-heteroacene up to a dodecamer in size. J. Mater. Chem. C, 2023, 11, 12900

29. Liu, J.;†Feng, Y.;†Yin, H.; He, T.;* Wang, K.; Long, G.; Yao, C.;* Strategy for Modulating Dihedral Angle Distribution for Enhanced Anti-Kasha TADF Behavior. J. Phys. Chem. C 2023, 127, 5567-5575

30. Huang, F.; He, T.; Li, M.; Meng, L.; Feng, W.; Liang, H.; Zhou,Y.; Wan, X.; Li, C.; Long, G.;* Yao, Z.;* Chen, Y.;* Can Isotope Effect Enable Organic Solar Cells to Achieve Smaller Non-Radiative Energy Losses and Why? Chem. Mater., 2022, 34, 6009-6025

31. Chen, H.;† Zou, Y.;† Liang, H.; He, T.; Xu, X.; Zhang, Y.; Ma, Z.; Wang, J.; Zhang, M.; Li, Q.; Li, C.; Long, G.;* Wan, X.; Yao, Z.;* Chen, Y.;* Lowing the energy loss of organic solar cells by molecular packing engineering via multiple molecular conjugation extension. Sci. China Chem., 2022, 65, pages1362-1373

32. Yang, B.; Wang, Z.; He, T.; Chen, J.; Mu, Z.; Ju, Z.; Lin, M.; Long, G.;* Zhang, J.;* Meng, H.;* Huang, W.; Chlorine substituted N-heteroacene analogues acting as organic semiconductors for solution-processed n-type organic field-effect transistors. Chem. Eur. J. 2022, e202201176

33. Liu, J.; Luo, C.; Lu, H.; Huang, Z.;* Long, G.;* Peng, X.;* Influence of hexagonal boron nitride on electronic structure of graphene. Molecules, 2022, 27, 3740

34. Zhai, X.; Wang, H.; Alekseevich, A.; Adamo, G.; Tian, J.; Gorkunov, M. V.; Soci, C.; Long, G.;* Proceedings Volume PC12322, Nanophotonics, Micro/Nano Optics, and Plasmonics VIII, 2022, https://doi.org/10.1117/12.2651357

35. Wang, L.; He, T.; Liao, H.; Luo, Y.; Ou, W.; Yu, Y.; Yue, W.; Long, G.; Wei, X.; Zhou, Y.;* A theoretical design of chiral molecules through conformational lock towards circularly polarized luminescence. Photonics 2022, 9, 532

36. Ma, S.; Li, G.;* Li, Z.; Zhang, Y.; Lu, H.; Gao, Z.; Wu, J.; Long, G.; Huang Y.* 2D Magnetic Semiconductor Fe₃GeTe₂ with Few and Single Layers with a Greatly Enhanced Intrinsic Exchange Bias by Liquid-Phase Exfoliation. ACS Nano 2022, 16, 19439

37. Yang, C.; Luo, L.; Chen, J.; Yang, B.; Wang, W.; Wang, H.; Long, G.; Liu, G. ; Zhang, J.;* Huang, W.* Helical Mesoscopic Crystals Based on Achiral Charge-Transfer Complex with Controllable Untwisting/Breaking. Chem. Commun., 2021, 57, 10031

38. Long, G.;† Adamo, G.;† Tian, J.; Klein, M.; Krishnamoorthy, Harish N. S.; Feltri, E.; Wang, H.; Soci, C.;* Perovskite metasurfaces with large superstructural chirality. Nat. Commun., 2022, 13, 1551.

39. Long, G.;† Adamo, G.;*† Tian, J.; Feltri, E.; Krishnamoorthy, Harish N. S.; Klein, M.; Soci, C.; All-dielectric Halide Perovskite Metasurfaces with Giant Chirality. OSA Technical Digest, 2021, DOI: 10.1364/CLEO_SI.2021.STu1C.2

40. Long, G.;† Sabatini, R.;† Saidaminov, M. I.;† Lakhwani, G.; Rasmita, A.; Liu, X.; Sargent, E. H.;* Gao, W.;* Chiral-perovskite optoelectronics. Nat. Rev. Mater. 2020, 5, 423

41. Long, G.;† Jiang, C.;† Sabatini, R.;† Yang, Z.;Wei, M.; Quan, L.; Liang, Q.;  Rasmita, A.; Askerka, M.; Walters, G.; Gong, X.; Xing, J.; Wen, X.; Quintero-Bermudez, R.; Yuan, H.; Xing, G.; Wang, X.; Song, D.; Voznyy, O.; Zhang, M.; Hoogland, S.; Gao, W.;* Xiong, Q.;* Sargent, E. H.;* Spin control in reduced-dimensional chiral perovskites. Nat. Photon., 2018, 12, 528-533.

42. Long, G.;*† Zhou, Y.;† Zhang, M.;†Sabatini, R.; Rasmita, A; Huang, L.; Lakhwani, G.; Gao, W.;* Theoretical prediction of chiral three-dimensional hybrid organic-inorganic perovskites. Adv. Mater., 2019, 31, 1807628.

43. Long, G.;† Wu, B.;† Ankur, S.; Yang, X.; Kan, B.; Liu, X.; Wan, X.; Li, M.; Sum, T.-C.;* Chen, Y.;* New insights into the correlation between morphology, excited state dynamics and device performance of small molecule organic solar cells. Adv. Energy Mater., 2016, 6, 1600961.

44. Long, G.; Wan, X.;* Kan, B.; Liu, Y.; He, G.; Li, Z.; Zhang, Y.-W.; Zhang, Y.; Zhang, Q.; Zhang, M.; Chen, Y.;* Investigation of quinquethiophene derivatives with different end groups for high open circuit voltage solar cells. Adv. Energy Mater., 2013, 3, 639-646.

45. Long, G.;† Li, A.;† Shi, R.; Zhou, Y.; Yang X.; Zuo, Y.; Wu, W.-R.; Jeng, U-S.; Wang, Y.; Wan, X.; Shen, P.; Zhang, H.; Yan, T.;* Chen, Y.;* The evidence for fullerene aggregation in high-performance small-molecule solar cells by molecular dynamics simulation. Adv. Electron. Mater.,2015, 1, 1500217.

46. Long, G.; Wan, X.;* Kan, B.; Hu, Z.; Yang, X.; Zhang, Y.; Zhang, M.; Wu, H.; Huang, F.; Su, S.; Cao, Y.; Chen, Y.;* Electron transport layer impact on the performance of solution processed small molecule organic solar cells. ChemSusChem., 2014, 7, 2358-2364.

47. Long, G.;† Wu, B.;† Yang, X.; Kan, B.; Zhou, Y.; Wan, X.; Chen, L.; Zhang, H.; Sum, T.-C.;* Chen, Y.;* The enhancement of performance and mechanism studies of all-solution processed small-molecule based solar cells with an inverted structure. ACS Appl. Mater. Interf., 2015, 7, 21245-21253.

48. Long, G.;† Zhou, Y.;† Jin, M.; Kan, B.; Zhang, Y.; Angus, G.-W.;* Jiang, D.-E.;* Chen, Y.;* Zhang, Q.;* Theoretical investigation on two-dimensional non-traditional carbon materials with three-membered ring and four-membered ring as building blocks. Carbon. 2015, 95, 1033-1038.

49. Long, G.; Yang, X.; Chen, W.; Zhang, M.;* Zhao, Y.;* Chen, Y.;* Zhang, Q.;* “Doping” pentacene with sp² phosphorus atoms: towards high performance ambipolar semiconductors.Phys. Chem. Chem. Phys., 2016, 18, 3173-3178.

50. Long, G.;† Shi, R.;† Zhou, Y.; Li, A.; Kan, B.; Wu, W.-R.; Jeng, U-S.; Xu, T.; Yan, T.; Zhang, M.; Yang, X.; Ke, X.; Sun, L.; Angus, G.-W.; Wan, X.; Zhang, H.; Li, C.; Wang, Y.;* Chen, Y.;* Molecular origin of donor- and acceptor-rich domain formation in bulk-heterojunction solar cells with an enhanced charge transport efficiency. J. Phys. Chem. C, 2017, 121, 5864-5870.

51. Jin, J.;† Long, G.;† Gao, Y.; Zhang, J.;* Ou, C.; Zhu, C.; Xu, H; Zhang, J;* Zhang, M.; Huang, W.;* Supramolecular Design of Donor-Acceptor Complexes via Heteroatom Replacement toward Structure and Electrical Transporting Property Tailoring. ACS Appl. Mater. Interf., 2019, 11, 1109-1116.

52. Hu, P.;† Long, G.;† Chaturvedi, A.;† Wang, S.; Tan, K. J.; He, Y.; Zheng, L.; Liu, G.; Ke, Y.; Zhou, Y.; Jiang, H.;* Liu, Z.; Zhang, M.; Long, Y.;* Agent-assisted VSSe ternary alloy single crystals towards efficient stable electrocatalyst for hydrogen evolution reaction. J. Mater. Chem. A, 2019, 7, 15714 - 15721.

53. Zhou, Y.;*† Long, G.;† Li, A.; Angus, G.-W.; Yan, T.; Chen, Y.; Towards predicting power conversion efficiencies of organic solar cells from donor and acceptor molecule structures. J. Mater. Chem. C, 2018, 6, 3276-3287.

54. Wan, X.; Long, G.; Huang, L.; Chen, Y.;* Graphene-a promising material for organic photovoltaic cells. Adv. Mater., 2011,23, 5342-5358. (Progress Report)

55.  Chen, Y.;* Wan, X.; Long, G. High performance photovoltaic applications using solution-processed small molecules. Acc. Chem. Res., 2013, 46, 2645-2655. (Review)

56.  Chen, W;† Li, X.;† Long, G.; Li, Y.; Ganguly, R.; Zhang, M.; Aratani, N.; Yamada, H.; Liu, M.;* Zhang, Q.:* Pyrene-containing twistarene: twelve benzene rings fused in a row. Angew. Chem. Int. Ed., 2018, 57, 13555-13559.

57. Wu, J.;† Rui, X.;† Long, G.; Chen, W.; Yan, Q.* and Zhang, Q.;* Pushing up lithium storage through nanostructured polyazaacene analogues as anode. Angew. Chem. Int. Ed., 2015, 54, 7354-7358.

58. Wang, C.;† Zhang, J.;† Long, G.; Aratani, N.; Yamada, H.; Zhao, Y.; Zhang, Q.;* Synthesis, structure, and air-stable N-type field-effect transistor behaviors of functionalized octaazanonacene-8,19-dione. Angew. Chem. Int. Ed., 2015, 54, 6292-6296.

59. Zhang, J.;† Wang, C.;† Long, G.; Aratani, N.; Yamada, H.; Zhang, Q.;* Fusing n-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing. Chem. Sci., 2016, 7, 1309-1313.

60. Zhang, J.;† Gu, P.;† Long, G.; Ganguly, R.; Li, Y.; Aratani, N.; Yamada, H.; Zhang, Q.;* Switching charge-transfer characteristic from p-type to n-type through molecule “doping” (co-crystallization). Chem. Sci., 2016, 7, 3851-3856

61. Zhang, Q.;† Kan, B.;† Liu, F.;† Long, G.; Wan, X.; Chen, X.; Zuo, Y.; Ni, W.; Zhang, H.; Li, M.; Hu, Z.; Huang, F.; Cao, Y.; Liang, Z.; Zhang, M.; Russell, T.; Chen, Y.;* Small-molecule solar cells with efficiency over 9%. Nat. Photon., 2015, 9, 35-41